I have the same issue.
The order actually says the IPN has been rec'd yet the order is still set to Pending.
Having said that, I notice there's a pile of additional Pending Statuses that are in the list such as Pending-53 - is that an old carry over from previous installations that could be causing this problem?
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Martin on "[Plugin: WooCommerce - excelling eCommerce] Downloads are pending after payment"
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